Here are all the Civilization 5 steam achievements, it could take you a long long looong time to get them all.
First In The Hearts Of Your Countrymen: Beat the game on any difficulty setting as Washington.
Video Et Taceo: Beat the game on any difficulty setting as Elizabeth.
Vivre La Revolution: Beat the game on any difficulty setting as Napoleon.
Blood And Iron: Beat the game on any difficulty setting as Bismarck.
Star Of The North: Beat the game on any difficulty setting as Catherine.
Veni, Vidi, Vici: Beat the game on any difficulty setting as Caesar.
The Man Who Would Be King: Beat the game on any difficulty setting as Alexander.
Amongst The Catacombs Of Nephren-ka: Beat the game on any difficulty setting as Ramesses II.
The African King: Beat the game on any difficulty setting as Askia.
Arabian Knights: Beat the game on any difficulty setting as Harun al-Rashid.
Age Of Empire: Beat the game on any difficulty setting as Darius.
Give Peace A Chance: Beat the game on any difficulty setting as Gandhi.
Empire Of The East: Beat the game on any difficulty setting as Ramkhamhaeng.
A Woman’s Work: Beat the game on any difficulty setting as Wu Zetian.
Rising Sun: Beat the game on any difficulty setting as Oda.
First Of The Mohicans: Beat the game on any difficulty setting as Hiawatha.
Montezuma’s Revenge…: Beat the game on any difficulty setting as Montezuma.
A Magnificent Victory: Beat the game on any difficulty setting as Suleiman.
Master Of The Universe: Beat the game on any difficulty setting with each leader.
Baby Steps: Beat the game on the Settler difficulty level.
Taking Off The Training Wheels: Beat the game on the Chieftain difficulty level.
The Alexman: Beat the game on the Warlord difficulty level.
Charming. Really.: Beat the game on the Prince difficulty level.
The Once And Future King: Beat the game on the King difficulty level.
The Golden Path: Beat the game on the Emperor difficulty level.
The World Is A Mess, And I Just Need To Rule It: Beat the game on the Immortal difficulty level.
Flawless Strategy: Beat the game on the Deity difficulty level.
It’s Just You And Me, Kid: Beat the game on a Duel Map.
I Need More Elbow Room: Beat the game on a Tiny Map.
Living In Smallville: Beat the game on a Small Map.
It’s Standard Issue: Beat the game on a Standard Map.
Do You Want To Super Size That?: Beat the game on a Large Map.
Ruler Of The Twelve Colonies: Beat the game on a Huge Map.
Plate Tectonics: Beat the game on a Continents-type Map.
Going It Old School: Beat the game on a Pangaea-type Map.
Island Hopping: Beat the game on an Archipelago-type Map.
Battlefield Earth: Beat the game on an Earth-type Map.
Gotta Catch ‘em All: Beat the game on all standard map types and sizes.
Last Man Standing: Win any Multiplayer Match.
Say Hello To My Little Friend: Reach Ally Status with a City State.
Neighborhood Bully: Annex a previously puppetted City State.
Engineer: Build a Wonder.
Harder, Better, Faster, Stronger: Upgrade a Unit.
Moving On Up: Earn a Unit Promotion.
Two Men Enter, One Man Leave: Completely defeat another Civ and remove them from the game.
Second City: Found a second city.
Treasure Hunter: Discover an ancient ruin.
We Have The Technology: Fully explore the Tech Tree.
The Wonder Years: Build all the Wonders, across any number of playthroughs.
Enlightened Ruler: Unlock all Social Policies, across any number of playthroughs.
Model Of A Modern Major-general: Train all Units, across any number of playthroughs.
Peace And Prosperity: Begin a Golden Age.
City Of Lights: Develop a city to produce more than 100 culture per turn.
City Of Science: Develop a city to produce more than 100 science per turn.
City Of Gold: Develop a city to produce more than 100 gold per turn.
Land Baron: Purchase 1000 tiles, across any number of playthroughs.
I’m On A Boat!: Embark a Unit.
Here Ends The Noble Savage: Raze 100 Barbarian camps, across any number of playthroughs.
Seriously?!?: Have another Civ beat you to completing a Wonder 10 times.
One To Rule Them All: Beat the game on any difficulty setting with only one city.
Go Boldly Where No Man Has Gone Before: Win a Space Victory.
The Best State Of A Republic: Win a Cultural Victory.
The Pen Is Mightier: Win a Diplomatic Victory.
Exterminate! Exterminate!: Win a Domination Victory.
To Stand The Test Of Time: Beat the game with all victory conditions.
I Can Has Nukes?: Drop a Nuke on another Civ.
Experimenter: Play a game with a Mod.
Expansionist: Download a Mod.
Connoisseur: Rate a Mod.
With Liberty And Justice For All: Fully Explore the Liberty Policy Track.
Lux Perpetua Luceat Eis: Fully Explore the Piety Policy Track.
Diplomacy By Other Means: Fully Explore the Autocracy Policy Track.
With An Iron Fist: Fully Explore the Order Policy Track.
Master Of The House: Fully Explore the Tradition Policy Track.
Death Before Shame: Fully Explore the Honor Policy Track.
Team Player: Fully Explore the Patronage Policy Track.
Money Doesn’t Grow On Trees: Fully Explore the Commerce Policy Track.
Eighty-eight Miles Per Hour: Fully Explore the Rationalism Policy Track.
Freedom Isn’t Free: Fully Explore the Freedom Policy Track.
The Explorer: Discover 100 Natural Wonders.
The Appian Way: Build 1000 roads, across any number of playthroughs.
Forty-niner: Build 1000 mines, across any number of playthroughs.
Merchant King: Trade 100 resources, across any number of playthroughs.
Magellan: Prove that the world is round by uncovering a connected loop of tiles around the circumference of the world.
Paul Bunyan: Chop down 1000 forest tiles, across any number of playthroughs.
God Is Great: Construct 1000 Temples, across any number of playthroughs.
Flying Fortress: Bomb an enemy city with a B-17.
Arab Trader: Trade a luxury resource to another Civ that you earned through a city with a Bazaar.
Gardens Of Lake Texcoco: Build a Floating Garden in a city with a lake tile in its radius.
Riddle Of The Sphinx: Rush a wonder as Egypt with a Great Engineer.
Three Musketeers: Kill a unit with a French Musketeer when two other Musketeers are providing flanking bonuses.
People Of The Longhouse: Build a longhouse in a city with at least 4 unchopped forests in its radius.
Bollywood: As Gandhi, win a cultural victory with 3 or fewer cities in your empire.
Kamikaze Attack: Kill an enemy unit attacking with a Japanese unit with just 1 HP remaining.
All Roads Lead To Rome: Build a road with a Roman Legion.
Sun Tzu’s Art Of War: As Wu Zetian, earn a Great General through battle.
Barbarian Warlord: As Bismarck, convert the Barbarians from 10 camps to your side.
Barbary Pirate: As Suleiman, accumulate a navy with 10 Barbarian naval units.
Tomb Raider: Pillage gold from an Egyptian city with a burial tomb in it.
My Little Pony: As Catherine, research Horseback Riding before any other Civ.
Ruler Of The Seas: As Elizabeth, sink and destroy 357 enemy naval units, across any number of playthroughs.
Conquest Of The World: As Alexander, defeat every known player by 350 BC.
He Threw A Car At My Head!: Have any city ransomed by Barbarians.
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